Did you know?
Mitochondria have their own DNA — evidence they were once independent bacteria absorbed by early cells.
Did you know?
Mitochondria have their own DNA — evidence they were once independent bacteria absorbed by early cells.
| Column I | Column II |
|---|---|
| A. [Co(NH₃)₅(NO₂)]Cl₂ | I. Solvate isomerism |
| B. [Co(NH₃)₅(SO₄)]Br | II. Linkage isomerism |
| C. [Co(NH₃)₆][Cr(CN)₆] | III. Ionization isomerism |
| D. [Cr(H₂O)₆]Cl₃ | IV. Coordination isomerism |
To solve this problem, we need to match the given complexes in List I with the types of isomerism in List II.Let's analyze each complex:A. • This complex can exhibit linkage isomerism. The ligand NO can bind through the nitrogen atom (nitro) or the oxygen atom (nitrito).• Therefore, A matches with II (Linkage isomerism).B. • This complex can exhibit ionization isomerism. The sulfate (SO) can be inside the coordination sphere, or it can be outside, swapping places with the bromide ion (Br).• Therefore, B matches with III (Ionization isomerism).C. • This complex can exhibit coordination isomerism. The cobalt and chromium can exchange their ligands, leading to different coordination entities.• Therefore, C matches with IV (Coordination isomerism).D. • This complex can exhibit solvate isomerism, where the water molecules can be part of the coordination sphere or outside it.• Therefore, D matches with I (Solvate isomerism).Thus, the correct matching is:A->II, B->III, C->IV, D->IThis corresponds to Option 3.
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