Did you know?
Diamonds and graphite are both made of pure carbon — just arranged differently.
Did you know?
Diamonds and graphite are both made of pure carbon — just arranged differently.
Mechanism of a hypothetical reaction is given below:(i)(fast)(ii)(slow)(iii)(fast)The overall order of the reaction will be
To determine the overall order of the reaction, we need to analyze the given reaction mechanism.The mechanism consists of three steps:(i) fast(ii) slow(iii) fastThe rate-determining step is the slowest step, which is step (ii).The rate law for the rate-determining step is determined by the reactants involved in that step.In step (ii), the reactants are and Therefore, the rate law can be written as:Rate To find the overall order of the reaction, we need to sum the exponents of the concentration terms in the rate law.The order with respect to is 1, and the order with respect to is 1.Thus, the overall order of the reaction is:However, we need to consider the equilibrium in step (ii).The equilibrium constant for the reversible step (ii) can affect the concentration of If we assume that the concentration of is in equilibrium with then:Substituting this into the rate law gives:Rate This simplifies to:Rate where Now, the order with respect to is and the order with respect to is 1.Therefore, the overall order of the reaction is:Thus, the correct option is Option 3.
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